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Early aging and age-related pathologies in mice deficient in BMAL1, the core component of the circadian clock
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1,4-Naphthoquinone ( 1 ) was treated with acetic acid in the presence of ammonium persulfate, as oxidizing agent, and silver(I) catalysis for only 1 hour, furnishing menadione ( 10 ) in 47% yield (Scheme 1)
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